Continuous flow submerged combustion melter cooling wall panels, submerged combustion melters, and methods of using same

ABSTRACT

Continuous flow submerged combustion melter cooling wall panels, including a primary metal plate, and several 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the 90 degree metal pieces having metal leg plates forming a 90 degree vertex there between. Each metal leg plate has an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent 90 degree metal piece. The plurality of 90 degree metal pieces may have a length (l) such that l&lt;L, each welded to the primary metal plate in staggered configuration to form, along with first and second end plates and a seal plate, a serpentine continuous flow coolant channel.

Cross-reference to related applications

This application is related to Applicant's U.S. Pat. No. 8,769,992, issued Jul. 8, 2014, and U.S. patent application Ser. No. 14/289,086, filed May 28, 2014, and Ser. No. 14/813,570, filed Jul. 30, 2015, all of which are incorporated herein by reference.

BACKGROUND INFORMATION Technical Field

The present disclosure relates to systems and methods for manufacture of glass products, mineral wool, rock wool, and other non-metallic inorganic materials using submerged combustion melters.

BACKGROUND ART

Submerged combustion melting (SCM) involves melting glass-forming materials, mineral wool forming materials, rock wool forming materials, and other non-metallic inorganic feedstock materials to produce molten materials by passing oxygen, oxygen-air mixtures or air along with a liquid, gaseous fuel, or particulate fuel directly into a molten or semi-molten pool of material, usually through burners submerged in a melt pool. The introduction of high flow rates of oxidant and fuel into the molten material, and the expansion of the gases cause rapid melting of the feedstock and much turbulence. Splashing of the molten vitreous mass inside the SCM is a phenomenon unique to the SCM. While aggressive mixing and turbulence are desired for reducing time to melt feedstock, this splashing (where molten material actually breaks away from the turbulent surface and travels upward and then fails back down into the vitreous mass by gravity, or strikes the ceding or walls of the SCM and drips back down into the molten mass, or solidifies thereon) causes significant strain on the materials of construction, such as fluid-cooled wall panels. This strain may open up unwanted passages in semi-continuous welded channels in traditional fluid-cooled (usually liquid-cooled) panels and allow cooling fluid to bypass sections of the panel. This may lead to boiling of the cooling liquid in the bypassed sections and the buildup of condensed material (solids) found in the cooling liquid that further may restrict cooling liquid flow.

It would be an advance in the SCM art if these bypassed sections in fluid-cooled panels could be reduced or eliminated.

SUMMARY

In accordance with the present disclosure, systems and methods are described which reduce or overcome one or more of the above problems.

A first aspect of the disclosure is a continuous flow submerged combustion melter cooling wall panel, in certain embodiments comprising (consisting essentially of, or consisting of):

a primary metal plate (preferably selected from carbon steel, stainless steel, or combinations thereof) having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality of substantially 90 degree metal (either same or different than the primary metal plate, preferably carbon steel, stainless steel, or combination thereof) pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

each of the plurality of substantially 90 degree metal pieces having a length (l) such that l<L, and each welded to the primary metal plate in staggered configuration to form, along with first and second end plates and a seal plate, a serpentine continuous flow coolant channel.

Certain other continuous flow submerged combustion melter cooling wall panels comprise (consist essentially of, or consist of):

a primary metal plate having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality of substantially 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

each of the plurality of substantially 90 degree metal pieces having a length (l) such that l=L, and each welded to the primary metal plate to form, along with first and second end plates, a plurality of substantially parallel, equal length coolant flow channels; and

a plurality of conduits fluidly connecting adjacent ends of the flow passages through the first and second end plates (or alternatively through the second leg of the substantially 90 degree metal pieces) and configured to form a serpentine continuous coolant flow channel.

Certain other continuous flow submerged combustion melter cooling wall panels comprise (or consist essentially of, or consist of):

a one piece milled metal plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of substantially parallel, equal length coolant flow channels milled or formed therein substantially parallel to longitudinal axis and not intersecting from a first end to a second end of the one piece milled metal plate, and

adjacent coolant flow channels connected at respective ends by a plurality of conduits fluidly connecting adjacent ends of the adjacent coolant flow channels and configured to form a serpentine continuous coolant flow channel.

Still other continuous flow submerged combustion melter cooling wall panels comprise (or consist essentially of, or consist of):

a one piece milled metal (pref. carbon steel) plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of non-through passages milled or formed therein substantially parallel to the longitudinal axis and not intersecting from a first end to the second end of the plate, the milled or formed non-through passages configured such that they extend from one minor edge of the plate to greater than 80 percent but not more than 99 percent of the length (L), adjacent through passages connected by surface conduits fluidly connected to the non-through passages by a plurality of connecting passages extending from one major surface to each of the non-through passages, and configured to produce a continuous coolant fluid flow passage through the plate.

A second aspect of the disclosure is a submerged combustion melter comprising (consisting of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels of the first aspect of this disclosure in either the roof, the sidewall structure, or both.

A third aspect of the disclosure is a method of producing molten inorganic product comprising feeding one or more feedstocks to an SCM of the second aspect of this disclosure.

Continuous flow submerged combustion melter cooling wall panels, SCMs, and methods of the disclosure will become more apparent upon review of the brief description of the drawings, the detailed description of the disclosure, and the claims that follow.

BRIEF DESCRIPTION OF THE DRAWINGS

The manner in which the objectives of the disclosure and other desirable characteristics can be obtained is explained in the following description and attached drawings in which:

FIG. 1 is a schematic perspective view of one embodiment of a fluid-cooled panel of this disclosure;

FIG. 2 is a schematic cross-sectional view of the burner of FIG. 1 along the line A-A;

FIG. 3 is a schematic cross-sectional view of the top portion of the burner of FIG. 1;

FIG. 4 is a schematic perspective view of another embodiment of a fluid-cooled panel of this disclosure;

FIG. 5 is a schematic plan view of one embodiment of a conditioning channel apparatus and system in accordance with this disclosure;

FIG. 6 is a schematic cross-sectional view along line C-C of FIG. 5;

FIGS. 7 and 8 are cross-sectional views along line B-B of FIG. 1 illustrating schematically two embodiments of conditioning channels in accordance with the present disclosure; and

FIG. 9 is a logic diagram of a method embodiment of the present disclosure.

It is to be noted, however, that the appended drawings are not to scale and illustrate only typical embodiments of this disclosure, and are therefore not to be considered limiting of its scope, for the disclosure may admit to other equally effective embodiments.

DETAILED DESCRIPTION

In the following description, numerous details are set forth to provide an understanding of the disclosed burners, burner panels, SCMs, and methods. However, it will be understood by those skilled in the art that the apparatus and methods covered by the claims may be practiced without these details and that numerous variations or modifications from the specifically described embodiments may be possible and are deemed within the claims. For example, wherever the term “comprising” is used, embodiments and/or components where “consisting essentially of” and “consisting of” are also explicitly disclosed herein and are part of this disclosure. An example of “consisting essentially of” may be with respect to the composition of a burner conduit: a conduit consisting essentially of carbon steel means there may be a minor portions or trace amounts of metals, oxides, and other chemical species that are noble metals, such chromium, platinum, and the like, and a conduit consisting essentially of noble metal may have trace amounts of iron, iron oxides, carbon, and other metal oxides. An example of “consisting of” may be a burner made up of components that are one or more carbon steels and no noble metals or ceramic materials, or conduits made up of only noble metals. Another example of “consisting essentially of” may be with respect to particulate feedstock that consists essentially of inorganic feedstock, meaning that a minor portion, perhaps up to 10, or up to 5, or up to 4, or up to 3, or up to 2, or up to 1 wt. percent may be organic. An example of methods and systems using the transition phrase “consisting of” includes those where only burners having liquid-cooled jackets are used, with no gas-cooled jackets, or vice versa. The term “comprising” and derivatives thereof is not intended to exclude the presence of any additional component, step or procedure, whether or not the same is disclosed herein. In order to avoid any doubt, all compositions, apparatus, systems, and methods claimed herein through use of the term “comprising” may include any additional component, step, or procedure unless stated to the contrary. In contrast, the term, “consisting essentially of” excludes from the scope of any succeeding recitation any other component, step or procedure, excepting those that are not essential to operability. The term “consisting of” excludes any component, step or procedure not specifically delineated or listed. The term “or”, unless stated otherwise, refers to the listed members individually as well as in any combination.

All references to the Periodic Table of the Elements herein shall refer to the Periodic Table of the Elements, published and copyrighted by CRC Press, Inc., 2003. Also, any references to a Group or Groups shall be to the Group or Groups reflected in this Periodic Table of the Elements using the IUPAC system for numbering groups. Unless stated to the contrary, implicit from the context, or customary in the art, all parts and percentages are based on weight and all test methods are current as of the filing date hereof. The acronym “ASTM” means ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, Pa., 19428-2959 USA.

All numbers, including degree angles, disclosed herein are approximate values, regardless whether the word “about” or “approximate” is used in connection therewith. They may vary by 1%, 2%, 5%, and sometimes, 10 to 20%. Whenever a numerical range with a lower limit, RL and an upper limit, RU, is disclosed, any number falling within the range is specifically disclosed. In particular, the following numbers within the range are specifically disclosed: R=RL+k*(RU−RL), wherein k is a variable ranging from 1% to 100% with a 1% increment, i.e., k is 1%, 2%, 3%, 4%, 5%, . . . , 50%, 51%, 52%, . . . , 95%, 96%, 97%, 98%, 99%, or 100%. Moreover, any numerical range defined by two R numbers as defined in the above is also specifically disclosed.

All U.S. patent applications and U.S. patents referenced herein are hereby explicitly incorporated herein by reference. In the event definitions of terms in the referenced patents and applications conflict with how those terms are defined in the present application, the definitions for those terms that are provided in the present application shall be deemed controlling. All percentages herein are based on weight unless otherwise specified.

As explained briefly in the Background, one drawback to submerged combustion is the tendency of the molten material to foam, either from glass-forming reactions, reactions pertaining to transformation of mineral and rock feedstocks into mineral wool and rock wool, combustion products, or combinations of these. Foams, especially glass foams, may stabilize in a top layer when the molten mass is routed through equipment downstream of the submerged combustion melter, such as forehearths, conditioning channels, distribution channels, and the like. The foam layer may impede the ability to apply heat to the molten or semi-molten material using combustion burners in the melter and in such downstream equipment, and may also impede the rate at which further bubbles in the melt rise and thus effect expulsion of the bubbles and mass flow rate of the melt in the channels. In extreme cases, the foam generated may interfere with the traditional energy application methods employed, in particular non-submerged low momentum combustion burners, which may cause systems to require shutdown, maintenance and may result in a process upset. Attempts to reduce the foam problem through process adjustments and panels have not met with complete success in reducing foam to an acceptable amount or acceptable burner life. In certain instances, accretions (build-up of solid or partially solidified material) on panel tips causes the flame from such burners to be deflected, reducing foam destruction efficiency as a melting campaign progresses. In drastic cases such flame deflection may cause melting or destruction of refractory linings of the SCM or flow channel.

Applicant has discovered fluid-cooled panels, systems and methods that may reduce or eliminate such problems.

Various terms are used throughout this disclosure. “Impingement” means that flames, combustion products, or oxidant (in embodiments where the velocity ratio of fuel to oxidant is 0) emanate from a burner tip above and strike an area or layer of foam floating on a molten mass of glass or other material being melted, and this flame, combustion product, or oxidant may emanate from a burner in a roof or sidewall of a melter or flow channel. “Impingement” or “auxiliary” burners as used herein are non-submerged combustion burners, and are either roof-mounted or wall-mounted, and in certain embodiments may be adjusted to deliver combustion products or oxidant either to foam layers at angles ranging from about 0 degrees (parallel to the foam layer) to about 90 degrees (perpendicular to the foam layer). “Submerged” as used herein means that combustion gases emanate from burner tips under the level of the molten material; submerged combustion (“SC”) burners may be floor-mounted, wall-mounted, roof-mounted, or in melter embodiments comprising more than one submerged combustion burner, any combination thereof (for example, two floor mounted burners and one wall mounted burner). “Wall” includes sidewalls and end wall unless otherwise noted.

The terms “foam” and “foamy” include froths, spume, suds, heads, fluffs, fizzes, lathers, effervesces, layer and the like. The term “bubble” means a thin, shaped, gas-filled film of molten material. The bubble shape may be spherical, hemispherical, rectangular, ovoid, and the like. Gas in the gas-filled bubbles may comprise oxygen or other oxidants, nitrogen, argon, noble gases, combustion products (including but not limited to, carbon dioxide, carbon monoxide, NO_(x), SO_(x), H₂S, and water), reaction products of glass-forming ingredients (for example, but not limited to, sand (primarily SiO₂), clay, limestone (primarily CaCO₃), burnt dolomitic lime, borax and boric acid, and the like, or reaction products of other feedstocks being melted, such as rock and minerals. Bubbles may include solids particles, for example soot particles, either in the film, the gas inside the film, or both.

As used herein the term “combustion gases” means substantially gaseous mixtures of combusted fuel, any excess oxidant, and combustion products, such as oxides of carbon (such as carbon monoxide, carbon dioxide), oxides of nitrogen, oxides of sulfur, and water. Combustion products may include liquids and solids, for example soot and unburned liquid fuels.

“Oxidant” as used herein includes air and gases having the same molar concentration of oxygen as air, oxygen-enriched air (air having oxygen concentration of oxygen greater than 21 mole percent), and “pure” oxygen, such as industrial grade oxygen, food grade oxygen, and cryogenic oxygen. Oxygen-enriched air may have 50 mole percent or more oxygen, and in certain embodiments may be 90 mole percent or more oxygen. Oxidants may be supplied from a pipeline, cylinders, storage facility, cryogenic air separation unit, membrane permeation separator, or adsorption unit.

The term “fuel”, according to this disclosure, means a combustible composition comprising a major portion of, for example, methane, natural gas, liquefied natural gas, propane, atomized oil or the like (either in gaseous or liquid form). Fuels useful in the disclosure may comprise minor amounts of non-fuels therein, including oxidants, for purposes such as premixing the fuel with the oxidant, or atomizing liquid fuels. As used herein the term “fuel” includes gaseous fuels, liquid fuels, flowable solids, such as powdered carbon or particulate material, waste materials, slurries, and mixtures or other combinations thereof. When the fuel comprises gaseous fuel, the gaseous fuel may be selected from the group consisting of methane, natural gas, liquefied natural gas, propane, carbon monoxide, hydrogen, steam-reformed natural gas, atomized oil or mixtures thereof.

The sources of oxidant and fuel may be one or more conduits, pipelines, storage facility, cylinders, or, in embodiments where the oxidant is air, ambient air. Oxygen-enriched oxidants may be supplied from a pipeline, cylinder, storage facility, cryogenic air separation unit, membrane permeation separator, or adsorption unit such as a vacuum swing adsorption unit.

Continuous flow submerged combustion melter cooling wall panel metal plates, various conduits, such as coolant, oxidant and fuel conduits, spacers, burner tip walls and crowns, feedstock supply conduits, and SCM exhaust conduits may be comprised of metal, ceramic, ceramic-lined metal, or combination thereof. Suitable metals include carbon steels, stainless steels, for example, but not limited to, 306 and 316 steel, as well as titanium alloys, aluminum alloys, and the like. High-strength materials like C-110 and C-125 metallurgies that are NACE qualified may be employed for burner body components. (As used herein, “NACE” refers to the corrosion prevention organization formerly known as the National Association of Corrosion Engineers, now operating under the name NACE International, Houston, Tex.) Use of high strength steel and other high strength materials may significantly reduce the conduit wall thickness required, reducing weight of the conduits and/or space required for conduits. In certain locations, precious metals and/or noble metals (or alloys) may be used for portions or all of these conduits. Noble metals and/or other exotic corrosion and/or fatigue-resistant materials such as platinum (Pt), ruthenium (Ru), rhodium (Rh), palladium (Pd), silver (Ag), osmium (Os), iridium (Ir), and gold (Au); alloys of two or more noble metals; and alloys of one or more noble metals with a base metal may be employed. In certain embodiments a protective layer or layers or components may comprise an 80 wt. percent platinum/20 wt. percent rhodium alloy attached to a base metal using brazing, welding or soldering of certain regions, as further explained in Applicant's U.S. patent application Ser. No. 14/778,206, filed Sep. 18, 2015. In certain embodiments carbon steel metal plates and conduits may be preferred as a low cost option.

The choice of a particular material is dictated among other parameters by the chemistry, pressure, and temperature of fuel and oxidant used and type of melt to be produced with certain feedstocks. The skilled artisan, having knowledge of the particular application, pressures, temperatures, and available materials, will be able design the most cost effective, safe, and operable heat transfer substructures, feedstock and exhaust conduits, burners, burner panels, and melters for each particular application without undue experimentation.

“Conduits” need not have a circular cross-section. SCMs need not have a rectangular cross-section or floor plan. The term “hydraulic diameter” means D_(H)=4A/P, where A is the cross-sectional area, and P is the wetted perimeter of the cross-section. Hydraulic diameter is mainly used for calculations involving turbulent flow, and for calculating Reynolds number, Re=ρuL/μ, where

-   -   L=D_(H),     -   μ=viscosity,     -   ρ=density, and         -   u=velocity.             Secondary flows (for example, eddies) can be observed in             non-circular conduits and vessels as a result of turbulent             shear stress in the fluid flowing through the conduit or             vessel experiencing turbulent flow. Hydraulic diameter is             also used in calculation of heat transfer in internal flow             problems. For a circular cross-section conduit, D_(H) equals             the diameter of the circle. For an annulus, D_(H) equals             D_(o)−D_(i), where D_(o) and D_(i) are the annulus outer             diameter and inner diameter, respectively. For a square             conduit having a side length of a, the D_(H) equals a. For a             fully filled conduit whose cross section is a regular             polygon, the hydraulic diameter is equivalent to the             diameter of a circle inscribed within the wetted perimeter.             “Turbulent conditions” means having a Re>4000, or greater             than 5000, or greater than 10,000, or greater than 20,000 or             higher. The phrase “the oxidant experiences a flow that is             turbulent” means the oxidant is flowing in turbulent manner             as it leaves the annulus and for a short distance (1 or             2 cm) thereafter so that eddies are maintained and             contribute to the bubble bursting effect. The phrase             “turbulent conditions in substantially all of the material             being melted” means that the SC burners and the SCM are             configured so that there may be some regions near the wall             and floor of the SCM where the material being melted will be             in transient or laminar flow as measured by Re, but the             majority (perhaps greater than 51%, or greater than 55%, or             greater than 6%, or greater than 65%, or greater than 70%,             or greater than 75%, or greater than 80% of the material             being melted will be experiencing turbulent flow. Transient             flow is defined as 2300<Re<4000, and laminar flow is defined             as Re<2300. The phrase “ejected portions of melted material”             means portions of the material being melted (or completely             molten material) that actually separate from the splash zone             and travel generally upward toward the SCM ceiling, or             toward the SCM walls above the splash zone, and even up into             the exhaust structure, then either solidify or drip back             down into the melt, or fall back into the melt after an             arcuate path upward, reaching a maximum, then falling back             into the melt, as in projectile motion.

Suitable materials for refractory fluid-cooled panels and SCM and flow channel refractory liners are fused zirconia (ZrO₂), fused cast AZS (alumina-zirconia-silica), rebonded AZS, or fused cast alumina (Al₂O₃). The geometry of the burner, SCM, or flow channel, and composition of molten material to be produced may dictate the choice of a particular material, among other parameters. Such refractory lining materials may include ceramics such as, but not limited to, alumina and silicon nitride, refractory materials such as, but not limited to, chrome-containing or zircon-based refractory metals, and noble metals, or mixtures or combinations thereof.

The term “fluid-cooled” means use of any coolant fluid (heat transfer fluid) to transfer heat away from the equipment in question, other than ambient air that resides naturally on the outside of the equipment. For example, portions of or the entire panels of sidewall structure, floor, and ceiling of the SCM and flow channels, skimmers, baffles, portions or all of heat transfer substructures used to preheat feedstock (for example nearest the melter), portions of feedstock supply conduits, and portions of SC burners, and the like may require fluid cooling. The terms “cooled” and “coolant” may include use of any heat transfer fluid and may be any gaseous, liquid, slurry, or some combination of gaseous, liquid, and slurry compositions that functions or is capable of being modified to function as a heat transfer fluid. Gaseous heat transfer fluids may be selected from air, including ambient air and treated air (for example, air treated to remove moisture), inorganic gases, such as nitrogen, argon, and helium, organic gases such as fluoro-, chloro- and chlorofluorocarbons, including perfluorinated versions, such as tetrafluoromethane, and hexafluoroethane, and tetrafluoroethylene, and the like, and mixtures of inert gases with small portions of non-inert gases, such as hydrogen. Heat transfer liquids may be selected from liquids that may be organic, inorganic, or some combination thereof, for example, salt solutions, glycol solutions, oils and the like. Other possible heat transfer fluids include steam (if cooler than the expected glass melt temperature), carbon dioxide, or mixtures thereof with nitrogen. Heat transfer fluids may be compositions comprising both gas and liquid phases, such as the higher chlorofluorocarbons. Certain SCMs and method embodiments of this disclosure may include fluid-cooled panels such as disclosed in Applicant's U.S. Patent No. 8,769,992.

Certain continuous flow submerged combustion melter cooling wall panels of this disclosure may comprise (or consist essentially of, or consist of):

a primary metal (pref. carbon steel) plate having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality (N) of substantially 90 degree metal (pref. carbon steel) pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

N-1 of the plurality of substantially 90 degree metal pieces having a length (l) such that l<L, and each welded to the primary metal plate in staggered configuration to form, along with first and second end plates, a seal plate, and one substantially 90 degree metal piece having l=L, a serpentine continuous flow coolant channel.

Certain continuous flow submerged combustion melter cooling wall panels include those wherein the first and second end plates are welded to respective first and second portions of the perimeter edge of the primary metal plate and to ends of alternating ones of the substantially 90 degree metal pieces and to first and second ends of the seal plate.] Certain continuous flow submerged combustion melter cooling wall panels include those wherein the first and second end plates are substantially 90 degree formed, machined, or bent end portions of the primary metal plate, and the seal plate is welded to an edge formed by the primary metal plate and the first and second end plates. Certain continuous flow submerged combustion melter cooling wall panels include those of wherein the first and second end plates are substantially 90 degree formed, machined, or bent end peripheral portions of the primary metal plate, and the seal plate is a substantially 90 degree formed, machined, or bent side peripheral portion of the primary metal plate, the seal plate having minor edges welded to minor edges of the first and second end plates. Certain continuous flow submerged combustion melter cooling wall panels include those wherein the plurality of substantially 90 degree metal pieces are each angle iron bent to an L-shape to form the first and second metal legs. Certain continuous flow submerged combustion melter cooling wall panels include those wherein the first and second metal leg plates are substantially equal in length. Certain continuous flow submerged combustion melter cooling wall panels include those wherein at least one of the plurality of substantially 90 degree metal pieces are configured to form at least one internal baffle. Certain continuous flow submerged combustion melter cooling wall panels include those having an arcuate shape viewed in plan. Certain continuous flow submerged combustion melter cooling wall panels include those having at least one additional layer attached to the panel away from the primary metal plate, the at least one additional layer selected form the group consisting of refractory, another layer of substantially 90 degree metal pieces welded to the plurality of substantially 90 degree metal pieces, and combinations thereof. Certain continuous flow submerged combustion melter cooling wall panels include those having at least one opening for positioning of a submerged combustion burner therein.

Certain continuous flow submerged combustion melter cooling wall panels may comprise (or consist essentially of, or consist of):

a primary metal plate having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality of substantially 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

each of the plurality of substantially 90 degree metal pieces having a length (l) such that l=L, and each welded to the primary metal plate to form, along with first and second end plates and a seal plate, a plurality of substantially parallel, equal length coolant flow channels; and

a plurality of conduits fluidly connecting adjacent ends of the flow passages through the first and second end plates and configured to form a serpentine continuous coolant flow channel.

Certain continuous flow submerged combustion melter cooling wall panels may comprise (or consist essentially of, or consist of):

a primary metal plate having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality of substantially 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

each of the plurality of substantially 90 degree metal pieces having a length (l) such that l=L, and each welded to the primary metal plate to form, along with first and second end plates and a seal plate, a plurality of substantially parallel, equal length coolant flow channels; and a plurality of conduits fluidly connecting adjacent ends of the flow passages through the second metal leg of the a plurality of substantially 90 degree metal pieces and configured to form a serpentine continuous coolant flow channel.

Certain continuous flow submerged combustion melter cooling wall panels may comprise (or consist essentially of, or consist of):

a one piece milled metal (pref. carbon steel) plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of substantially parallel, equal length coolant flow channels milled or formed therein substantially parallel to longitudinal axis and not intersecting from a first end to a second end of the one piece milled metal plate, and

adjacent coolant flow channels connected at respective ends by a plurality of conduits fluidly connecting adjacent ends of the adjacent coolant flow channels and configured to form, a serpentine continuous coolant flow channel.

Certain continuous flow submerged combustion melter cooling wall panels include those wherein each of the coolant flow channels has a diameter (D) less than (T) with the proviso that D is 1 inch or greater. Certain continuous flow submerged combustion melter cooling wall panels may include those wherein each of the coolant flow channels are substantially identical in diameter, length and shape. Certain continuous flow submerged combustion melter cooling wall panels include those wherein the coolant flow channels are separated by distance of no more than 3 inches (or no more than 2 inches, or no more than 1 inch, or no more than 0.5 inch). Certain continuous flow submerged combustion melter cooling wall panels include those wherein the coolant flow channels have a cross-section selected from the group consisting of circular, semi-circular, polygonal, trapezoidal, triangular, irregular, and combinations thereof. Certain continuous flow submerged combustion melter cooling wall panels include those having an arcuate shape viewed in plan. Certain continuous flow submerged combustion melter cooling wall panels include those having at least one additional layer attached to the one piece milled metal plate, the at least one additional layer selected from the group consisting of refractory, a second one piece milled metal plate, and combinations thereof. Certain continuous flow submerged combustion melter cooling wall panels include those having at least one opening for positioning of a submerged combustion burner therein.

Certain continuous flow submerged combustion melter cooling wall panels may comprise (or consist essentially of, or consist of): a one piece milled metal (pref. carbon steel) plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of non-through passages milled or formed therein substantially parallel to the longitudinal axis and not intersecting from a first end to the second end of the plate, the milled or formed non-through passages configured such that they extend from one minor edge of the plate to greater than 80 percent but not more than 99 percent of the length (L), adjacent through passages connected by surface conduits fluidly connected to the non-through passages by a plurality of connecting passages extending from one major surface to each of the non-through passages, and configured to produce a continuous coolant fluid flow passage through the plate.

Submerged combustion melters may comprise (or consist of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels of this disclosure in the SCM floor, roof, the sidewall structure, or any combination of these.

Methods of producing molten inorganic product comprising feeding one or more feedstocks to an SCM of this disclosure, melting the feedstock using turbulent submerged combustion, and discharging the molten inorganic product from the SCM are considered another aspect of this disclosure. Methods comprising routing warmed coolant from one or more of the continuous flow submerged combustion melter cooling wall panels of this disclosure installed in an SCM to a feedstock preheater, a fuel preheater, an oxidant preheater, or combination thereof, are considered another aspect of this disclosure.

Specific non-limiting apparatus, system and method embodiments in accordance with the present disclosure will now be presented in conjunction with FIGS. 1-9. The same numerals are used for the same or similar features in the various figures. In the views illustrated in FIGS. 1-8, it will be understood in each case that the figures are schematic in nature, and certain conventional features are not illustrated in order to illustrate more clearly the key features of each embodiment.

FIGS. 1-5 are schematic exploded perspective views illustrating five embodiments 100, 200, 300, 400, and 500, respectively, of continuous flow submerged combustion melter cooling wall panels of this disclosure (preferably liquid-cooled, preferably water-cooled). Embodiment 100 illustrating schematically in FIG. 1 features a primary metal plate 2 having a length (L), width (W), and thickness (t), having a first major surface 4 and a second major surface (not illustrated) opposite surface 4, and a perimeter edge 6. A seal plate 8, a plurality of substantially 90 degree metal pieces 10, and first and second end plates 16, 18 are welded together to form the final structure having a length (L), width (W), and thickness (T). Only welds 12 and 14 are illustrated, welds 12 forming a plurality of junctions of a plurality of first metal leg plates 24 and primary metal plate 2, while welds 14 form a plurality of junctions between distal ends of a plurality of second metal leg plates 26, as indicated.

Embodiment 100 is characterized primarily by all but one of the substantially 90 degree metal pieces having a length (l) such that l<L, and the substantially 90 degree metal pieces are offset such that when coolant is introduced through inlet port 22 the coolant follows a serpentine path through the structure until exiting through outlet port 20. It will easily be recognized that the coolant flow direction could be reversed in certain embodiments.

Embodiments 200 and 300 illustrated schematically in FIGS. 2 and 3 in exploded perspective views, respectively, differ from embodiment 100 of FIG. 1 by each having l=L. Embodiment 200 further includes a coolant inlet conduit 28, a coolant outlet conduit 30, and a plurality of U-bends 32 for fluidly connecting the coolant flow passages formed between each of the substantially 90 degree metal plates 10. Conduits 28, 30, and U-bends 32 may be the same or different metal as primary metal plate 2 and end plates 16, 18, as further explained herein, and may be welded, brazed, or soldered to end plates 16, 18. Embodiment 300 differs from embodiment 200 by attaching the U-bends 32 and conduits 28, 30 to the second metal leg plate 26 of each substantially 90 degree metal piece as illustrated, it being understood there are two through holes in each metal leg plate 26, one near each end thereof, for passage of coolant. One advantage of the structure of embodiment 300 is that the cooling panels may be butted against one another when constructing the SCM, since there is no hardware protruding from end plates 16, 18.

FIGS. 6 and 6A are close-up side elevation views illustrating the use of angle iron and welding to form the structures of embodiments 100, 200, and 300. Angle iron pieces 10 are available commercially having a substantially 90 degree angle “α” between first and second metal leg pieces 24, 26. A distal end of leg 24 from vertex (V) may be beveled as illustrated and welded to primary metal plate 2, and a distal end of leg 26 may be beveled and welded to the vertex of the next angle iron piece.

Embodiments 400 and 500 feature a one piece milled metal (pref. carbon steel) plate 2 having a length (L), width (W), a thickness (T), a longitudinal axis (LA), a central or vertical axis (CA), a first major surface 4 and an opposite major surface (not illustrated), and a perimeter edge having end faces 38A, 38B and top and bottom faces 39A, 39B. The one piece milled metal plate 2 of embodiment 400 includes a plurality of substantially parallel, equal length coolant flow channels 36 milled or formed therein of length L substantially parallel to the longitudinal axis (LA) and substantially perpendicular to the central axis (CA), and not intersecting from the first end face 38A to a second end face 38B of the one piece milled metal plate 2. Embodiment 400 feature adjacent coolant flow channels 36 connected at respective ends by a plurality of conduits 32 (for example U-bends) fluidly connecting adjacent ends of adjacent coolant flow channels 36 and configured to form a serpentine continuous coolant flow channel when coolant is introduced into conduit 28 and exits conduit 30 (or vice versa). Embodiment 500 differs from embodiment 400 in that it features a plurality of substantially parallel coolant flow channels 36 milled or formed therein of length l<L substantially parallel to the longitudinal axis (LA) and substantially perpendicular to the central axis (CA), and not intersecting from the first end face 38A to a second end face 38B of the one piece milled metal plate 2, and the coolant conduits 28, 30, and 32 are welded, brazed or otherwise fitted onto major surface 4 of the one piece milled metal plate 2, or fitted into through holes in one piece milled metal plate 2 so that a serpentine continuous coolant flow channel when coolant is introduced into conduit 28 and exits conduit 30 (or vice versa). Embodiment 500 presents the same advantage as embodiment 300 in that the panels may be butted against one another in constructing the SCM.

FIG. 7 illustrates in perspective view a metal plate useful in constructing embodiments 100, 200, and 300, and illustrates that a single metal plate 2 may be molded or stamped into the shape illustrated in the upper portion of FIG. 7 (it being understood that holes 20, 22 would not be required for embodiment 300). Metal plate 2 could be stamped or molded, then bent in one or multiple steps to the shape illustrated in the lower portion of FIG. 7, thus eliminating the requirement of welding, brazing, or other heat-joining steps to join end plates 16, 18 and seal plate 8 to primary metal plate 2, as well as avoiding possible accelerated corrosion areas during operation of the SCM.

The various dimensions of the continuous flow submerged combustion melter cooling wall panels of the present disclosure may have values in accordance with Table 1, it being understood that these are merely examples, and other dimensions may be employed outside of these ranges.

TABLE 1 Dimensions of continuous flow submerged combustion melter cooling wall panels Embodiment Feature 100 200 300 400 500 L 0.25-10 m 0.25-10 m 0.25-10 m 0.25-10 m 0.25-10 m 1.0-5 m 1.0-5 m 1.0-5 m 1.0-5 m 1.0-5 m W 0.1-5 m 0.1-5 m 0.1-5 m 0.1-5 m 0.1-5 m 1.0-2 m 1.0-2 m 1.0-2 m 1.0-2 m 1.0-2 m t 0.1-20 cm 0.1-20 cm 0.1-20 cm N/A N/A 1-5 cm 1-5 cm 1-5 cm T 5-40 cm 5-40 cm 5-40 cm 5-40 cm 5-40 cm 10-30 cm 10-30 cm 10-30 cm 10-30 cm 10-30 cm I 0.5 L-.95 L I = L I = L I = L 0.5 L-.95 L 0.7-0.9 L 0.7-0.9 L D_(H), hydraulic 1-10 cm 1-10 cm 1-10 cm 1-10 cm 1-10 cm diameter of 2-5 cm 2-5 cm 2-5 cm 2-5 cm 2-5 cm flow channel α  75-125 75-125 75-125 N/A N/A 85-95 85-95  85-95 

FIG. 8 is a schematic flow diagram of one SCM embodiment 600 and method in according to the present disclosure. Embodiment 600 illustrates an SCM 40, a feedstock supply 42 feeding the SCM through a feedstock chute 44 and feedstock inlet 45, the SCM having a ceiling or roof 46, a sidewall structure 48, and a floor 50, the sidewall structure connecting the roof 46 to the floor 50, and a melt outlet port 52 illustrated in phantom. Also illustrated schematically are SC burners 54, 56 of the pipe-in-pipe arrangement with fuel flowing through an inner conduit and oxidant through an outer conduit, it being understood that any SC burners could be used, as further disclosed herein, and that the flow of oxidant could rather be in the inner pipe and the flow of fuel in the outer pipe. A cooling water inlet (CWI) conduit 58 provides cooling water to a three-way control valve 96, having outlet conduits 60, 62. Outlet conduit supplies cooling water to continuous flow submerged combustion cooling panel 100, while conduit 62 may route a portion of the cooling water to a stack cooler 64 that serves to cool stack gases passing through SCM stack 66 in accordance with this embodiment. Warmed cooling water may then be routed from stack cooler 64 through a conduit 68 to another three-way control valve 97, and all or a portion routed to cooling water return (CWR) conduit 70, or optionally a portion may be routed through conduit 72 to a feedstock preheater 74 prior to being routed to cooling water return through conduit 71. Feedstock preheater may be a shell or jacket around feed chute 44, or more sophisticated heat exchanger. Warmed cooling water, or cooling water outlet (CWO) from continuous flow submerged combustion cooling panel 100 (there may be more than one such panel per SCM) may be routed through a conduit 88 to a four-way control valve 98, and separate portions of the warmed cooling water routed through conduits 90, 92 and used to preheat oxidant (OX) and/or fuel (F) using heat exchangers 80, 82, respectively. Fuel may be routed through a supply conduit 76 to heat exchanger 82, and warmed fuel through conduits 86, 87 to burners 54, 56. Similarly, or alternatively, feed oxidant may proceed through conduit 78 to heat exchanger 80, and warned oxidant routed to SC burners 54, 56, though conduits 84, 85. A portion or all of warmed cooling water may also be routed through a conduit 94 to preheat feedstock.

It will be appreciated by those skilled in the art that many modifications of the scheme illustrated in FIG. 8 may be envisioned, and these variations are considered within the present disclosure. For example, all of the warmed cooling water or other coolant may be employed to preheat feedstock, rather than being used to preheat fuel or oxidant. Some or all of the warmed coolant may be used to vaporized oxidant, for example liquid oxygen. In certain embodiments, SC burners may be installed n the continuous flow cooling panels, and the coolant employed to cool parts of the burners.

It should furthermore be understood that embodiments 100-500 are only one example of many possible cooling panel shapes. Suitable shaped panels of metal may have any longitudinal shape (straight, L-shaped, curved, for example S-shaped), and may have one or more parallel and/or series arranged regions.

The flow rate of the coolant through channels in the cooling panels will depend on many factors, including the dimensions of channels, size of SC melter and the cooling panels, whether or not there are baffles in the channels, temperature of the melt and the coolant, and like parameters, but in general the flow rate of coolant will increase as the flow rate of feedstock and combustion products from the SC burners increases, and decrease accordingly when those parameters decrease.

FIG. 9 is a logic diagram of one method embodiment 700 of the present disclosure, including the steps of (box 902) routing one or more feedstocks to a submerged combustion melter (SCM) comprising (consisting of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels in the roof, the floor, or the sidewall structure, or any combination thereof, the continuous flow submerged combustion melter cooling wall panel comprising a primary metal (pref. carbon steel) plate having length (L), a width (W), first and second major surfaces, and a perimeter edge; a plurality (N) of substantially 90 degree metal (pref. carbon steel) pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece; N-1 of the plurality of substantially 90 degree metal pieces having a length (l) such that l<L, and each welded to the primary metal plate in staggered configuration to form, along with first and second end plates, a seal plate, and one substantially 90 degree metal piece having l=L, a serpentine continuous flow coolant channel. Method embodiment 900 further comprises producing molten inorganic product by melting the feedstock in the SCM using one or more SC burners producing turbulent submerged combustion conditions in the SCM (box 904); discharging the molten inorganic product from the SCM (box 906); at least partially cooling the sidewalls of the SCM by feeding coolant through the at least one continuous flow submerged combustion melter cooling wall panels, forming warmed coolant (box 908); and optionally routing some or all of the warmed coolant from one or more of the continuous flow submerged combustion melter cooling wall panels to a feedstock preheater, a fuel preheater, an oxidant preheater, or combination thereof (box 910). It will be understood that methods using other embodiments of continuous flow submerged combustion cooling panels, and embodiments wherein two or more types of continuous flow submerged combustion cooling panels in accordance with the present disclosure, are with in the present disclosure.

Submerged combustion melter 40 in embodiments described herein may be any of the currently known submerged combustion melter designs, or may be one of those described in Applicant's U.S. Pat. No. 8,769,992, incorporated herein by reference, as long as they include at least one continuous flow submerged combustion cooling panel in accordance with the present disclosure. Submerged combustion melters useful in the practice of the methods and apparatus of this description may take any number of forms, including those described in Applicant's U.S. Pat. No. 8,769,992, which describes sidewalls forming an expanding melting zone formed by a first trapezoidal region, and a narrowing melting zone formed by a second trapezoidal region, wherein a common base between the trapezoid defines the location of the maximum width of the melter. Submerged combustion melter 40 may include a roof, sidewalls, a floor or bottom, one or more submerged combustion burners, an exhaust system (for example, such as described in Applicant's U.S. Pat. No. 8,707,740), one or more molten product outlet structures (for example, such as described in Applicant's U.S. Pat. No. 9,145,319), and optionally one or more non-fluid-cooled panels comprising some or all of the sidewalls. Submerged combustion melter 40 is typically supported on a plant floor.

Submerged combustion melter 40 may be fed a variety of feed materials by one or more roll stands, which in turn supports one or more rolls of glass mat, as described in Applicant's U.S. Pat. No. 8,650,914. In certain embodiments powered nip rolls may include cutting knives or other cutting components to cut or chop the mat (or roving, in those embodiments processing roving) into smaller length pieces prior to entering melter 40. Also provided in certain embodiments may be a glass batch feeder. Glass batch feeders are well-known in this art and require no further explanation. Certain embodiments may comprise a process control scheme for the submerged combustion melter and burners. For example, as explained in the '914 patent, a master process controller may be configured to provide any number of control logics, including feedback control, feed-forward control, cascade control, and the like. The disclosure is not limited to a single master process controller, as any combination of controllers could be used. The term “control”, used as a transitive verb, means to verify or regulate by comparing with a standard or desired value. Control may be closed loop, feedback, feed-forward, cascade, model predictive, adaptive, heuristic and combinations thereof. The term “controller” means a device at least capable of accepting input from sensors and meters in real time or near-real time, and sending commands directly to burner control elements, and/or to local devices associated with burner control elements and glass mat feeding devices able to accept commands. A controller may also be capable of accepting input from human operators; accessing databases, such as relational databases; sending data to and accessing data in databases, data warehouses or data marts; and sending information to and accepting input from a display device readable by a human. A controller may also interface with or have integrated therewith one or more software application modules, and may supervise interaction between databases and one or more software application modules. The controller may utilize Model Predictive Control (MPC) or other advanced multivariable control methods used in multiple input/multiple output (MIMO) systems. The methods of Applicant's U.S. Pat. No. 8,973,400, using the vibrations and oscillations of the melter itself, and U.S. Pat. No. 9,096,453, using temperature control, may prove useful predictive control inputs.

Those having ordinary skill in this art will appreciate that there are many possible variations of the melter, continuous flow cooling panels, burners, heat exchangers, and control mechanisms, and will be able to devise alternatives and improvements to those described herein that are nevertheless considered to be within the claims of the present patent.

Submerged combustion burners useful in the SC melter apparatus described herein include those described in U.S. Pat. Nos. 4,539,034; 3,170,781; 3,237,929; 3,260,587; 3,606,825; 3,627,504; 3,738,792; 3,764,287; and 7,273,583, and Applicant's U.S. Pat. Nos. 8,875,544 and 9,032,760. One useful burner, for example, is described in the '583 patent as comprising a method and apparatus providing heat energy to a bath of molten material and simultaneously creating a well-mixed molten material. The burner functions by firing a burning gaseous or liquid fuel-oxidant mixture into a volume of molten material. The burners described in the '583 patent provide a stable flame at the point of injection of the fuel-oxidant mixture into the melt to prevent the formation of frozen melt downstream as well as to prevent any resultant explosive combustion; constant, reliable, and rapid ignition of the fuel-oxidant mixture such that the mixture burns quickly inside the molten material and releases the heat of combustion into the melt; and completion of the combustion process in bubbles rising to the surface of the melt. SC burners such as described in Applicant's co-pending U.S. patent application Ser. Nos. 14/785,327; 14/785,325; 14/785,330; and 14/785,324, all filed Oct. 17, 2015 (the first featuring reduced stress and thermal fatigue of the top toroid shape, the second featuring Pt/Rh or Cu-alloy based burners tips and attachment to the remainder of the burner, usually carbon steel; and the third featuring burners having improved fuel and oxidant mixing; and the fourth featuring a toroid burner tip and protective cap for same) may be used. Other SC burners that may be used include the SC burners described in Applicant's U.S. patent applications Ser. No. 14/904,662, filed Jan. 1, 2016 (featuring attaching a toroid burner tip to the body of the burner using interlocking rings) and Ser. No. 14/784,995, filed Oct. 15, 2015 (featuring a concave burner tip crown); Ser. No. 14/778,206. filed Sep. 18, 2015 (featuring a spin-formed or stamped burner tip); the SC burners and burner panels described in Applicant's U.S. patent application Ser. Nos. 14/838,148 and 14/838,229, both filed Aug. 27, 2015; and the SC burners described in Applicant's U.S. patent application Ser. No. 15/246,705, filed Aug. 25, 2016 (JM 8369).

In certain embodiments the SC burners may be floor-mounted burners. In certain embodiments, the SC burners may be positioned in rows substantially perpendicular to the longitudinal axis (in the melt flow direction) of melter 40. In certain embodiments, the SC burners may be positioned to emit combustion products into molten glass in a melting zone of melter 40 in a fashion so that the gases penetrate the melt generally perpendicularly to the floor. In other embodiments, one or more burners may emit combustion products into the melt at an angle to the floor, as taught in Applicant's U.S. Pat. No. 8,769,992.

Submerged combustion melters useful in systems and methods in accordance with the present disclosure may also comprise one or more wall-mounted submerged combustion burners, and/or one or more roof-mounted non-submerged combustion burners or burner panels. Roof-mounted non-submerged combustion burners and panels may be useful to pre-heat the melter apparatus melting zone, and serve as ignition sources for one or more submerged combustion burners. Melters having only wall-mounted, submerged-combustion burners are also considered within the present disclosure. Roof-mounted burners may be oxy-fuel burners, but as they are only used in certain situations, are more likely to be air/fuel burners. Most often they would be shut-off after pre-heating the melter and/or after starting one or more submerged combustion burners. In certain embodiments, if there is a possibility of carryover of particles to the exhaust, one or more roof-mounted burners could be used to form a curtain to prevent particulate carryover. In certain embodiments, all submerged combustion burners may be oxy/fuel burners (where “oxy” means oxygen, or oxygen-enriched air, as described earlier), but this is not necessarily so in all embodiments; some or all of the submerged combustion burners may be air/fuel burners. Furthermore, heating may be supplemented by electrical heating in certain melter embodiments, in certain melter zones, and in the lehr. In certain embodiments the oxy-fuel burners may comprise one or more submerged combustion burners each having co-axial fuel and oxidant tubes forming an annular space there between, wherein the outer tube extends beyond the end of the inner tube, as taught in U.S. Pat. No. 7,273,583. Burners may be flush-mounted with the melter floor in certain embodiments. In other embodiments, such as disclosed in the '583 patent, a portion of one or more of the burners may extend slightly into the melt above the melter floor.

In certain embodiments, melter side walls may have a free-flowing form, devoid of angles. In certain other embodiments, side walls may be configured so that an intermediate location may comprise an intermediate region of melter 40 having constant width, extending from a first trapezoidal region to the beginning of a narrowing melting region. Other embodiments of suitable melters are described in the above-mentioned '992 patent.

The continuous flow submerged combustion melter cooling panels of the present disclosure may include a thin refractory liner on major surface facing inward toward the molten material inside the SCM, which minimizes heat losses from the melter, but allows formation of a thin frozen glass shell to form on the surfaces and prevent any refractory wear and associated molten product contamination. In certain embodiments, the continuous flow submerged combustion melter cooling wall panel may be cooled by a heat transfer fluid selected from the group consisting of gaseous, liquid, or combinations of gaseous and liquid compositions that functions or is capable of being modified to function as a heat transfer fluid. Gaseous heat transfer fluids may be selected from air, including ambient air and treated air (for air treated to remove moisture), inert inorganic gases, such as nitrogen, argon, and helium, inert organic gases such as fluoro-, chloro- and chlorofluorocarbons, including perfluorinated versions, such as tetrafluoromethane, and hexafluoroethane, and tetrafluoroethylene, and the like, and mixtures of inert gases with small portions of non-inert gases, such as hydrogen. Heat transfer liquids may be selected from water, inert liquids that may be organic, inorganic, or some combination thereof, for example, salt solutions, glycol solutions, oils and the like. Water is the preferred heat transfer fluid. Other possible heat transfer fluids include steam (if cooler than the oxygen manifold temperature), carbon dioxide, or mixtures thereof with nitrogen. Heat transfer fluids may be compositions comprising both gas and liquid phases, such as the higher chlorofluorocarbons.

Continuous flow submerged combustion melter cooling wall panel metal plates and conduits, when in alloyed form, may comprise alloys of two or more noble metals that may have any range of noble metals. For example, alloys of two noble metals may have a range of about 0.01 to about 99.99 percent of a first noble metal and 99.99 to 0.01 percent of a second noble metal. Any and all ranges in between 0 and 99.99 percent first noble metal and 99.99 and 0 percent second noble metal are considered within the present disclosure, including 0 to about 99 percent of first noble metal; 0 to about 98 percent; 0 to about 97 percent; 0 to about 96; 0 to about 95; 0 to about 90; 0 to about 80; 0 to about 75; 0 to about 70; 0 to about 65; 0 to about 60; 0 to about 55; 0 to about 50; 0 to about 45, 0 to about 40; 0 to about 35; 0 to about 30; 0 to about 25; 0 to about 20; 0 to about 19; 0 to about 18; 0 to about 17; 0 to about 16; 0 to about 15; 0 to about 14; 0 to about 13; 0 to about 12; 0 to about 11; 0 to about 10; 0 to about 9; 0 to about 8; 0 to about 7; 0 to about 6; 0 to about 5; 0 to about 4; 0 to about 3; 0 to about 2; 0 to about 1; and 0 to about 0.5 percent of a first noble metal; with the balance comprising a second noble metal, or consisting essentially of (or consisting of) a second noble metal (for example with one or more base metals present at no more than about 10 percent, or no more than about 9 percent base metal, or no more than about 8, or about 7, or about 6, or about 5, or about 4, or about 3, or about 2, or no more than about 1 percent base metal).

In certain noble metal alloy embodiments comprising three or more noble metals, the percentages of each individual noble metal may range from equal amounts of all noble metals in the composition (about 33.33 percent of each), to compositions comprising, or consisting essentially of, or consisting of 0.01 percent of a first noble metal, 0.01 percent of a second noble metal, and 99.98 percent of a third noble metal. Any and all ranges in between about 33.33 percent of each, and 0.01 percent of a first noble metal, 0.01 percent of a second noble metal, and 99.98 percent of a third noble metal, are considered within the present disclosure.

Embodiments disclosed herein include:

A: A continuous flow submerged combustion melter cooling panel comprising:

a primary metal (pref. carbon steel) plate having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality (N) of substantially 90 degree metal (pref. carbon steel) pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

N-1 of the plurality of substantially 90 degree metal pieces having a length (l) such that l<L, and each welded to the primary metal plate in staggered configuration to form, along with first and second end plates, a seal plate, and one substantially 90 degree metal piece having l=L, a serpentine continuous flow coolant channel.

B: A continuous flow submerged combustion melter cooling panel comprising:

a primary metal plate having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality of substantially 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

each of the plurality of substantially 90 degree metal pieces having a length (l) such that l=L, and each welded to the primary metal plate to form, along with first and second end plates and a seal plate, a plurality of substantially parallel, equal length coolant flow channels; and

a plurality of conduits fluidly connecting adjacent ends of the flow passages through the first and second end plates and configured to form a serpentine continuous coolant flow channel.

C: A continuous flow submerged combustion melter cooling panel comprising:

a primary metal plate having length (L), a width (W), first and second major surfaces, and a perimeter edge;

a plurality of substantially 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece;

each of the plurality of substantially 90 degree metal pieces having a length (l) such that l=L, and each welded to the primary metal plate to form, along with first and second end plates and a seal plate, a plurality of substantially parallel, equal length coolant flow channels; and

a plurality of conduits fluidly connecting adjacent ends of the flow passages through the second metal leg of the a plurality of substantially 90 degree metal pieces and configured to form a serpentine continuous coolant flow channel.

D: A continuous flow submerged combustion melter cooling panel comprising: a one piece milled metal (pref. carbon steel) plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of substantially parallel, equal length coolant flow channels milled or formed therein substantially parallel to longitudinal axis and not intersecting from a first end to a second end of the one piece milled metal plate, and

adjacent coolant flow channels connected at respective ends by a plurality of conduits fluidly connecting adjacent ends of the adjacent coolant flow channels and configured to form, a serpentine continuous coolant flow channel.

E: A continuous flow submerged combustion melter cooling panel comprising:

a one piece milled metal (pref. carbon steel) plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of non-through passages milled or formed therein substantially parallel to the longitudinal axis and not intersecting from a first end to the second end of the plate, the milled or formed non-through passages configured such that they extend from one minor edge of the plate to greater than 80 percent but not more than 99 percent of the length (L), adjacent through passages connected by surface conduits fluidly connected to the non-through passages by a plurality of connecting passages extending from one major surface to each of the non-through passages, and configured to produce a continuous coolant fluid flow passage through the plate.

Embodiments A, B and C may have one or more of the following additional elements in any combination: Element 1: the first and second end plates are welded to respective first and second portions of the perimeter edge of the primary metal plate and to ends of alternating ones of the substantially 90 degree metal pieces and to first and second ends of the seal plate. Element 2: the first and second end plates are substantially 90 degree formed, machined, or bent end portions of the primary metal plate, and the seal plate is welded to an edge formed by the primary metal plate and the first and second end plates. Element 3: the first and second end plates are substantially 90 degree formed, machined, or bent end peripheral portions of the primary metal plate, and the seal plate is a substantially 90 degree formed, machined, or bent side peripheral portion of the primary metal plate, the seal plate having minor edges welded to minor edges of the first and second end plates. Element 4: the plurality of substantially 90 degree metal pieces are each angle iron bent to an L-shape to form the first and second metal legs. Element 5: the first and second metal leg plates are substantially equal in length. Element 6: at least one of the plurality of substantially 90 degree metal pieces are configured to form at least one internal baffle. Element 7: the continuous flow submerged combustion melter cooling wall panel has an arcuate shape viewed in plan. Element 8: the continuous flow submerged combustion melter cooling wall panel has at least one additional layer attached to the panel away from the primary metal plate, the at least one additional layer selected form the group consisting of refractory, another layer of substantially 90 degree metal pieces welded to the plurality of substantially 90 degree metal pieces, and combinations thereof. Element 9: the continuous flow submerged combustion melter cooling wall panel has at least one opening for positioning of a submerged combustion burner therein.

Embodiments D and E may have one or more of the following additional elements in any combination: Element 1: each of the coolant flow channels has a diameter (D) less than (T) with the proviso that D is 1 inch (2.5 cm) or greater. Element 2: each of the coolant flow channels are substantially identical in diameter, length and shape. Element 3: the coolant flow channels are separated by distance of no more than 3 inches (or no more than 2 inches, or no more than 1 inch, or no more than 0.5 inch). Element 4: the coolant flow channels have a cross-section selected from the group consisting of circular, semi-circular, polygonal, trapezoidal, triangular, irregular, and combinations thereof. Element 5: the continuous flow submerged combustion melter cooling wall panel has an arcuate shape viewed in plan. Element 6: the continuous flow submerged combustion melter cooling wall panel has at least one additional layer attached to the one piece milled metal plate, the at least one additional layer selected from the group consisting of refractory, a second one piece milled metal plate, and combinations thereof. Element 7: the continuous flow submerged combustion melter cooling wall panel has at least one opening for positioning of a submerged combustion burner therein.

All of embodiments A, B, C, D, and E may be installed in an SCM, and all may be used in methods of making molten products (glass products, mineral products, rock products) using the SCM. All of the SCM embodiments may employ one or more heat recovery schemes described herein, alone or in combination.

Although only a few exemplary embodiments of this disclosure have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel apparatus and processes described herein. Accordingly, all such modifications are intended to be included within the scope of this disclosure as defined in the following claims. In the claims, no clauses are intended to be in the means-plus-function format allowed by 35 U.S.C. § 112(f) unless “means for” is explicitly recited together with an associated function. “Means for” clauses are intended to cover the structures described herein as performing the recited function and not only structural equivalents, but also equivalent structures. 

What is claimed is:
 1. A continuous flow submerged combustion melter cooling wall panel comprising: a primary metal (pref. carbon steel) plate having length (L), a width (W), first and second major surfaces, and a perimeter edge; a plurality (N) of substantially 90 degree metal (pref. carbon steel) pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece; N-1 of the plurality of substantially 90 degree metal pieces having a length (l) such that l<L, and each welded to the primary metal plate in staggered configuration to form, along with first and second end plates, a seal plate, and one substantially 90 degree metal piece having l=L, a serpentine continuous flow coolant channel.
 2. The continuous flow submerged combustion melter cooling wall panel of claim 1 wherein the first and second end plates are welded to respective first and second portions of the perimeter edge of the primary metal plate and to ends of alternating ones of the substantially 90 degree metal pieces and to first and second ends of the seal plate.
 3. The continuous flow submerged combustion melter cooling wall panel of claim 1 wherein the first and second end plates are substantially 90 degree formed, machined, or bent end portions of the primary metal plate, and the seal plate is welded to an edge formed by the primary metal plate and the first and second end plates.
 4. The continuous flow submerged combustion melter cooling wall panel of claim 1 wherein the first and second end plates are substantially 90 degree formed, machined, or bent end peripheral portions of the primary metal plate, and the seal plate is a substantially 90 degree formed, machined, or bent side peripheral portion of the primary metal plate, the seal plate having minor edges welded to minor edges of the first and second end plates.
 4. The continuous flow submerged combustion melter cooling wall panel of claim 1 wherein the plurality of substantially 90 degree metal pieces are each angle iron bent to an L-shape to form the first and second metal legs.
 5. The continuous flow submerged combustion melter cooling wall panel of claim 4 wherein the first and second metal leg plates are substantially equal in length.
 6. The continuous flow submerged combustion melter cooling wall panel of claim 1 wherein at least one of the plurality of substantially 90 degree metal pieces are configured to form at least one internal baffle.
 7. The continuous flow submerged combustion melter cooling wall panel of claim 1 having an arcuate shape viewed in plan.
 8. The continuous flow submerged combustion melter cooling wall panel of claim 1 having at least one additional layer attached to the panel away from the primary metal plate, the at least one additional layer selected form the group consisting of refractory, another layer of substantially 90 degree metal pieces welded to the plurality of substantially 90 degree metal pieces, and combinations thereof.
 9. The continuous flow submerged combustion melter cooling wall panel of claim 1 having at least one opening for positioning of a submerged combustion burner therein.
 10. A continuous flow submerged combustion melter cooling wall panel comprising: a primary metal plate having length (L), a width (W), first and second major surfaces, and a perimeter edge; a plurality of substantially 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece; each of the plurality of substantially 90 degree metal pieces having a length (l) such that l=L, and each welded to the primary metal plate to form, along with first and second end plates and a seal plate, a plurality of substantially parallel, equal length coolant flow channels; and a plurality of conduits fluidly connecting adjacent ends of the flow passages through the first and second end plates and configured to form a serpentine continuous coolant flow channel.
 11. The continuous flow submerged combustion melter cooling wall panel of claim 10 wherein the first and second end plates are welded to respective first and second portions of the perimeter edge of the primary metal plate and to ends of the substantially 90 degree metal pieces and to first and second ends of the seal plate.
 12. The continuous flow submerged combustion melter cooling wall panel of claim 10 wherein the first and second end plates are substantially 90 degree formed, machined, or bent end portions of the primary metal plate, and the seal plate is welded to an edge formed by the primary metal plate and the first and second end plates.
 13. The continuous flow submerged combustion melter cooling wall panel of claim 10 wherein the first and second end plates are substantially 90 degree formed, machined, or bent end peripheral portions of the primary metal plate, and the seal plate is a substantially 90 degree formed, machined, or bent side peripheral portion of the primary metal plate, the seal plate having minor edges welded to minor edges of the first and second end plates.
 14. The continuous flow submerged combustion melter cooling wall panel of claim 10 wherein the plurality of substantially 90 degree metal pieces are each angle iron bent to an L-shape to form the first and second metal legs.
 15. The continuous flow submerged combustion melter cooling wall panel of claim 14 wherein the first and second metal leg plates are substantially equal in length.
 16. The continuous flow submerged combustion melter cooling wall panel of claim 10 wherein at least one of the plurality of substantially 90 degree metal pieces are configured to form at least one internal baffle.
 17. The continuous flow submerged combustion melter cooling wall panel of claim 10 having an arcuate shape viewed in plan.
 18. The continuous flow submerged combustion melter cooling wall panel of claim 10 having at least one additional layer attached to the panel away from the primary metal plate, the at least one additional layer selected form the group consisting of refractory, another layer of substantially 90 degree metal pieces welded to the plurality of substantially 90 degree metal pieces, and combinations thereof.
 19. The continuous flow submerged combustion melter cooling wall panel of claim 10 having at least one opening for positioning of a submerged combustion burner therein.
 20. A continuous flow submerged combustion melter cooling wall panel comprising: a primary metal plate having length (L), a width (W), first and second major surfaces, and a perimeter edge; a plurality of substantially 90 degree metal pieces welded to the primary metal plate in parallel configuration, each of the substantially 90 degree metal pieces comprising first and second metal leg plates configured to form a substantially 90 degree vertex therebetween, each metal leg plate having an edge distal to the vertex, the distal edge of the first metal leg plate welded to the first major surface of the primary metal plate, the distal edge of the second metal leg plate welded to the vertex of an adjacent substantially 90 degree metal piece; each of the plurality of substantially 90 degree metal pieces having a length (l) such that l=L, and each welded to the primary metal plate to form, along with first and second end plates and a seal plate, a plurality of substantially parallel, equal length coolant flow channels; and a plurality of conduits fluidly connecting adjacent ends of the flow passages through the second metal leg of the a plurality of substantially 90 degree metal pieces and configured to form a serpentine continuous coolant flow channel.
 21. A continuous flow submerged combustion melter cooling wall panel comprising: a one piece milled metal (pref. carbon steel) plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of substantially parallel, equal length coolant flow channels milled or formed therein substantially parallel to longitudinal axis and not intersecting from a first end to a second end of the one piece milled metal plate, and adjacent coolant flow channels connected at respective ends by a plurality of conduits fluidly connecting adjacent ends of the adjacent coolant flow channels and configured to form, a serpentine continuous coolant flow channel.
 22. The continuous flow submerged combustion melter cooling wall panel of claim 21 wherein each of the coolant flow channels has a diameter (D) less than (T) with the proviso that D is 1 inch or greater.
 23. The continuous flow submerged combustion melter cooling wall panel of claim 21 wherein each of the coolant flow channels are substantially identical in diameter, length and shape.
 24. The continuous flow submerged combustion melter cooling wall panel of claim 21 wherein the coolant flow channels are separated by distance of no more than 3 inches (or no more than 2 inches, or no more than 1 inch, or no more than 0.5 inch).
 25. The continuous flow submerged combustion melter cooling wall panel of claim 21 wherein the coolant flow channels have a cross-section selected from the group consisting of circular, semi-circular, polygonal, trapezoidal, triangular, irregular, and combinations thereof.
 26. The continuous flow submerged combustion melter cooling wall panel of claim 21 having an arcuate shape viewed in plan.
 27. The continuous flow submerged combustion melter cooling wall panel of claim 21 having at least one additional layer attached to the one piece milled metal plate, the at least one additional layer selected from the group consisting of refractory, a second one piece milled metal plate, and combinations thereof.
 28. The continuous flow submerged combustion melter cooling wall panel of claim 21 having at least one opening for positioning of a submerged combustion burner therein.
 29. A continuous flow submerged combustion melter cooling wall panel comprising: a one piece milled metal (pref. carbon steel) plate having a length (L), width (W), a longitudinal axis, a thickness (T), first and second major surfaces, and a perimeter edge, the one piece milled metal plate comprising a plurality of non-through passages milled or formed therein substantially parallel to the longitudinal axis and not intersecting from a first end to the second end of the plate, the milled or formed non-through passages configured such that they extend from one minor edge of the plate to greater than 80 percent but not more than 99 percent of the length (L), adjacent through passages connected by surface conduits fluidly connected to the non-through passages by a plurality of connecting passages extending from one major surface to each of the non-through passages, and configured to produce a continuous coolant fluid flow passage through the plate.
 30. A submerged combustion melter comprising (consisting of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels of claim 1 in either the roof, the sidewall structure, or both.
 31. A submerged combustion melter comprising (consisting of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels of claim 10 in either the roof, the sidewall structure, or both.
 32. A submerged combustion melter comprising (consisting of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels of claim 20 in either the roof, the sidewall structure, or both.
 33. A submerged combustion melter comprising (consisting of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels of claim 21 in either the roof, the sidewall structure, or both.
 34. A submerged combustion melter comprising (consisting of, or consisting essentially of) one or more continuous flow submerged combustion melter cooling wall panels of claim 29 in either the roof, the sidewall structure, or both.
 35. A method of producing molten inorganic product comprising feeding one or more feedstocks to the SCM of claim 30, melting the feedstock using turbulent submerged combustion, and discharging the molten inorganic product from the SCM.
 36. A method of producing molten inorganic product comprising feeding one or more feedstocks to the SCM of claim 31, melting the feedstock using turbulent submerged combustion, and discharging the molten inorganic product from the SCM.
 37. A method of producing molten inorganic product comprising feeding one or more feedstocks to the SCM of claim 32, melting the feedstock using turbulent submerged combustion, and discharging the molten inorganic product from the SCM.
 38. A method of producing molten inorganic product comprising feeding one or more feedstocks to the SCM of claim 33, melting the feedstock using turbulent submerged combustion, and discharging the molten inorganic product from the SCM.
 39. A method of producing molten inorganic product comprising feeding one or more feedstocks to the SCM of claim 34, melting the feedstock using turbulent submerged combustion, and discharging the molten inorganic product from the SCM.
 40. The method of claim 35 comprising routing warmed coolant from one or more of the continuous flow submerged combustion melter cooling wall panels to a feedstock, preheater, a fuel preheater, an oxidant preheater, or combination thereof.
 41. The method of claim 36 comprising routing warmed coolant from one or more of the continuous flow submerged combustion melter cooling wall panels to a feedstock, preheater, a fuel preheater, an oxidant preheater, or combination thereof.
 42. The method of claim 37 comprising routing warmed coolant from one or more of the continuous flow submerged combustion melter cooling wall panels to a feedstock, preheater, a fuel preheater, an oxidant preheater, or combination thereof.
 43. The method of claim 38 comprising routing warmed coolant from one or more of the continuous flow submerged combustion melter cooling wall panels to a feedstock, preheater, a fuel preheater, an oxidant preheater, or combination thereof.
 44. The method of claim 39 comprising routing warmed coolant from one or more of the continuous flow submerged combustion melter cooling wall panels to a feedstock, preheater, a fuel preheater, an oxidant preheater, or combination thereof. 